Literaturnachweis - Detailanzeige
| Autor/inn/en | Kirschenbaum, Louis J.; Ruekberg, Ben |
|---|---|
| Titel | Relating Bond Angles of Dihalo- and Tetrahydro--Methanes, -Silanes, and -Germanes to Electronegativities |
| Quelle | In: Journal of Chemical Education, 89 (2012) 3, S.351-354 (4 Seiten)Infoseite zur Zeitschrift
PDF als Volltext |
| Sprache | englisch |
| Dokumenttyp | gedruckt; online; Zeitschriftenaufsatz |
| ISSN | 0021-9584 |
| DOI | 10.1021/ed200355u |
| Schlagwörter | Science Instruction; College Science; Scientific Principles; Correlation; Undergraduate Study; Inorganic Chemistry; Molecular Structure; Energy |
| Abstract | Our previous work correlated bond angles of group V and group VI hydrides (AH[subscript 3]E and AH[subscript 2]E[subscript 2], respectively, where E represents a lone electron pair) to the electronegativities of the atoms using the fraction of s character to relate the two. Here we have extended the correlation to the AH[subscript 2]X[subscript 2] series, where A is a group IV atom, carbon, silicon, or germanium and X is hydrogen, fluorine, chlorine, bromine, or iodine, treating each "X" as an individual series. These group IV series are correlated to each other by the atomic radius and electronegativity of the "X" (halide or hydrogen) atom, yielding a single relationship for all of fourteen compounds. The results support three assertions (and their corollaries) that allow students to predict relative hybridization and, thus, bond angles of these dihalides based on readily available electronegativity values. (Contains 2 tables and 2 figures.) (As Provided). |
| Anmerkungen | Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc |
| Erfasst von | ERIC (Education Resources Information Center), Washington, DC |
| Update | 2017/4/10 |
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