Synthesis and Use of a Nickel Oxidation Catalyst Using Glove Box Methods

Autor/inn/en	Weiss, Charles J.; Porter, Lon A., Jr.
Titel	Synthesis and Use of a Nickel Oxidation Catalyst Using Glove Box Methods
Quelle	In: Journal of Chemical Education, 97 (2020) 6, S.1655-1659 (5 Seiten)Infoseite zur Zeitschrift PDF als Volltext Verfügbarkeit
Zusatzinformation	ORCID (Weiss, Charles J.) ORCID (Porter, Lon A., Jr.)
Sprache	englisch
Dokumenttyp	gedruckt; online; Zeitschriftenaufsatz
ISSN	0021-9584
Schlagwörter	Science Instruction; Scientific Concepts; Undergraduate Study; College Science; Science Laboratories; Metallurgy; Spectroscopy; Inorganic Chemistry; Science Process Skills; Science Experiments + Suchen Sie Ihr Suchwort? Teaching of science; Science education; Natural sciences Lessons; Naturwissenschaftlicher Unterricht; Grundstudium; Hüttenwesen; Spektroskopie; Anorganische Chemie
Abstract	The ability to perform air-free chemistry and catalytic reactions on an NMR tube scale are valuable skills in chemistry and not often included in undergraduate chemistry curriculum. This laboratory experiment provides students experience in synthesizing the metal complex, Ni(dcpe)(CH[subscript 3]CN)[subscript 2](BF[subscript 4])[subscript 2] (dcpe = 1,2-bis(dicyclohexylphosphino)ethane), inside an inert atmosphere glovebox, performing a catalytic alcohol oxidation reaction on a microscale, and monitoring the reaction progress by [superscript 1]H NMR spectroscopy. This activity has been employed in the Advanced Inorganic Chemistry course at Wabash College for three years. The reactions have proven to be reliable, and the students have gained valuable experience using advanced techniques common in inorganic chemistry research laboratories. (As Provided).
Anmerkungen	Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Erfasst von	ERIC (Education Resources Information Center), Washington, DC
Update	2024/1/01