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Autor/inn/en | Prabpal, Jutamat; Vilaivan, Tirayut; Praneenararat, Thanit |
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Titel | Paper-Based Heavy Metal Sensors from the Concise Synthesis of an Anionic Porphyrin: A Practical Application of Organic Synthesis to Environmental Chemistry |
Quelle | In: Journal of Chemical Education, 94 (2017) 8, S.1137-1142 (6 Seiten)Infoseite zur Zeitschrift
PDF als Volltext |
Zusatzinformation | ORCID (Praneenararat, Thanit) |
Sprache | englisch |
Dokumenttyp | gedruckt; online; Zeitschriftenaufsatz |
ISSN | 0021-9584 |
DOI | 10.1021/acs.jchemed.6b00943 |
Schlagwörter | Organic Chemistry; Paper (Material); Metallurgy; Advanced Courses; Undergraduate Students; College Science; Science Instruction; Science Experiments; Hands on Science; Laboratory Experiments; Spectroscopy |
Abstract | Tetrakis(4-sulfonatophenyl)porphyrin (TSPP) was immobilized on patterned paper and used as a sensor for heavy metal ions in an advanced organic chemistry course. The resulting sensor could detect Hg[superscript 2+] and Cd[superscript 2+] ions colorimetrically, while Cu[superscript 2+] ion resulted in fluorescence quenching, thus demonstrating a multiplex capability of this paper-based sensor. From the synthesis of the porphyrin to the fabrication of the sensor, advanced undergraduate chemistry students gained first-hand experience with a classical organic synthesis, and also witnessed its application within 2-3 full-day laboratory sessions. This experiment is a good demonstration of how an easily synthesized compound can be exploited to tackle an important problem in real-world situations. (As Provided). |
Anmerkungen | Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc |
Erfasst von | ERIC (Education Resources Information Center), Washington, DC |
Update | 2020/1/01 |