Literaturnachweis - Detailanzeige
| Autor/inn/en | Whited, Matthew T.; Hofmeister, Gretchen E. |
|---|---|
| Titel | Synthesis and Migratory-Insertion Reactivity of CpMo(CO)[subscript3](CH[subscript3]): Small-Scale Organometallic Preparations Utilizing Modern Glovebox Techniques |
| Quelle | In: Journal of Chemical Education, 91 (2014) 7, S.1050-1053 (4 Seiten)Infoseite zur Zeitschrift
PDF als Volltext |
| Sprache | englisch |
| Dokumenttyp | gedruckt; online; Zeitschriftenaufsatz |
| ISSN | 0021-9584 |
| DOI | 10.1021/ed500114a |
| Schlagwörter | College Science; Science Instruction; Inorganic Chemistry; Metallurgy; Science Experiments; Laboratory Experiments; Undergraduate Students; Laboratory Equipment; Laboratory Procedures; Spectroscopy |
| Abstract | Experiments are described for the reliable small-scale glovebox preparation of CpMo(CO)[subscript 3](CH[subscript 3]) and acetyl derivatives thereof through phosphine-induced migratory insertion. The robust syntheses introduce students to a variety of organometallic reaction mechanisms and glovebox techniques, and they are easily carried out during three laboratory meetings. Furthermore, the series of complexes offers several interesting case studies for symmetry analysis of IR and NMR spectra. (As Provided). |
| Anmerkungen | Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc |
| Erfasst von | ERIC (Education Resources Information Center), Washington, DC |
| Update | 2017/4/10 |
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