Literaturnachweis - Detailanzeige
| Autor/inn/en | Evans, Alexandra L.; Messersmith, Reid E.; Green, David B.; Fritsch, Joseph M. |
|---|---|
| Titel | Degradation of Environmental Contaminants with Water-Soluble Cobalt Catalysts: An Integrative Inorganic Chemistry Investigation |
| Quelle | In: Journal of Chemical Education, 88 (2011) 2, S.204-208 (5 Seiten)Infoseite zur Zeitschrift
PDF als Volltext |
| Sprache | englisch |
| Dokumenttyp | gedruckt; online; Zeitschriftenaufsatz |
| ISSN | 0021-9584 |
| DOI | 10.1021/ed1005344 |
| Schlagwörter | Inorganic Chemistry; Water Pollution; Laboratory Experiments; Science Experiments; College Science; Science Instruction |
| Abstract | We present an integrative laboratory investigation incorporating skills from inorganic chemistry, analytical instrumentation, and physical chemistry applied to a laboratory-scale model of the environmental problem of chlorinated ethylenes in groundwater. Perchloroethylene (C[subscript 2]Cl[subscript 4], PCE) a common dry cleaning solvent, undergoes sequential replacement of Cl with H to trichloroethylene (C[subscript 2]HCl[subscript 3]) and subsequently "cis"-dichloroethylene (C[subscript 2]H[subscript 2]Cl[subscript 2]) through catalytic reductive dechlorination with water-soluble cobalt complexes. PCE degradation is monitored by gas chromatography and the first-order rate constants are determined. Experimental conditions may be varied to optimize chlorinated ethylene dechlorination and explore the important parameters governing degradation. Students work with reduction-oxidation active compounds and analyze "real-world" kinetic data sets. (Contains 2 tables and 3 figures.) (As Provided). |
| Anmerkungen | Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc |
| Erfasst von | ERIC (Education Resources Information Center), Washington, DC |
| Update | 2017/4/10 |
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