Literaturnachweis - Detailanzeige
Autor/inn/en | Orofino, Hugo; Faria, Roberto B. |
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Titel | Obtaining the Electron Angular Momentum Coupling Spectroscopic Terms, jj |
Quelle | In: Journal of Chemical Education, 87 (2010) 12, S.1451-1454 (4 Seiten)Infoseite zur Zeitschrift
PDF als Volltext |
Sprache | englisch |
Dokumenttyp | gedruckt; online; Zeitschriftenaufsatz |
ISSN | 0021-9584 |
DOI | 10.1021/ed1004245 |
Schlagwörter | Science Instruction; Spectroscopy; Molecular Structure; Scientific Concepts; Nuclear Energy; Teaching Methods; College Science; Chemistry |
Abstract | A systematic procedure is developed to obtain the electron angular momentum coupling (jj) spectroscopic terms, which is based on building microstates in which each individual electron is placed in a different m[subscript j] "orbital". This approach is similar to that used to obtain the spectroscopic terms under the Russell-Saunders (LS) coupling scheme when the electrons are placed on m[subscript l] orbitals. Using the procedure presented in this article, the students gain greater familiarity with jj coupling, which is a better description for the atomic electronic states of heavy atoms and many excited states of heavy and light atoms. This approach reinforces the conceptual understanding of the meaning of the spectroscopic terms in broader terms. (Contains 10 tables.) (As Provided). |
Anmerkungen | Division of Chemical Education, Inc and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc |
Erfasst von | ERIC (Education Resources Information Center), Washington, DC |
Update | 2017/4/10 |