Synthesis, Characterization, and Property Investigation of a Metal-Organic Framework Encapsulated Polyoxometalate Guests: An Advanced Inorganic Chemistry Experiment

Autor/inn/en	Yuan, Min; Sun, Chun-Yan; Liu, Yi-Wei; Lu, Ying; Zhang, Zhong; Li, Xiao-Hui; Tian, Hong-Rui; Zhang, Shan; Liu, Shu-Xia
Titel	Synthesis, Characterization, and Property Investigation of a Metal-Organic Framework Encapsulated Polyoxometalate Guests: An Advanced Inorganic Chemistry Experiment
Quelle	In: Journal of Chemical Education, 97 (2020) 11, S.4152-4157 (6 Seiten)Infoseite zur Zeitschrift PDF als Volltext Verfügbarkeit
Zusatzinformation	ORCID (Liu, Shu-Xia)
Sprache	englisch
Dokumenttyp	gedruckt; online; Zeitschriftenaufsatz
ISSN	0021-9584
Schlagwörter	Inorganic Chemistry; Science Experiments; Laboratory Experiments; Advanced Students; Undergraduate Students; Science Process Skills; Skill Development; Molecular Structure + Suchen Sie Ihr Suchwort? Anorganische Chemie; Laboratory work; Laborarbeit; Fortgeschrittener; Kompetenzentwicklung; Qualifikationsentwicklung
Abstract	A research-style laboratory experiment for advanced undergraduate students is described, which includes the synthesis, characterization, and properties (porosity, stability, amphipathy) testing of the composite [Cu[subscript 2](BTC)[subscript 4/3](H[subscript 2]O)[subscript 2][subscript 6][HPW[subscript 12]O[subscript 40]·(C[subscript 4]H[subscript 12]N)[subscript 2]·25H[subscript 2]O (denoted as NENU-3, H[subscript 3]BTC = 1,3,5-benzenetricarboxylic acid). This experiment lets students experience the universal procedure of hydro(solvo)-thermal synthesis and get knowledge of general scientific research approaches as well as have hands-on experiences in diverse modern instrumental techniques (PXRD, IR and UV--vis spectroscopy, N[subscript 2] adsorption, and TG analysis) extensively used in chemical research. Most importantly, this laboratory experiment exposes students to explore the structure-property-application relationship in NENU-3 composite material through comparing the structure and properties of NENU-3 with those of its individual component materials (H[subscript 3]PW[subscript12]O[subscript 40] and Cu[subscript 3](BTC)[subscript 2]) and consulting the related literature about NENU-3 catalysis. This experiment is helpful for developing the scientific thinking of students in chemistry through completing the analysis and discussion about the structure-property-application relationship in POM@MOF. (As Provided).
Anmerkungen	Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Erfasst von	ERIC (Education Resources Information Center), Washington, DC
Update	2024/1/01